First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

古太平洋板块俯冲-增生时限：饶河增生杂岩的地球化学和年代学制约   总被引：1，自引：1，他引：0  

韩伟  周建波 《岩石学报》2020,36(3):703-725

饶河杂岩作为那丹哈达增生杂岩的主体,是古太平洋板块西向俯冲的直接证据。饶河增生杂岩组成与增生过程的研究对限定古太平洋板块向欧亚大陆的俯冲与增生过程具有重要的指示意义。本文在野外地质调查和饶河大岱地区大比例尺填图基础上,明确了饶河杂岩主要由枕状玄武岩、辉长岩以及大洋板块沉积地层(OPS)组成,这些岩石均呈构造透镜体状分布在海沟沉积物中,并被中生代花岗质岩脉所穿切,因此为限定饶河增生杂岩的组成、增生和就位时代提供了关键制约。地球化学数据表明玄武岩具有洋岛玄武岩(OIB)的地球化学属性。LA-ICPMS锆石测试结果表明该地区玄武岩和辉长岩的形成时代分别为166±2Ma和214±5Ma,限定了饶河杂岩中镁铁质-超镁铁质岩石的形成时代为晚三叠世至中侏罗世。结合该区粉砂质泥岩和砂岩的沉积时代下限分别为167±3Ma和133±4Ma,表明饶河杂岩的增生时代为167～133Ma,此外样品的碎屑年龄信息表明基质的物源为邻近的佳木斯地块和中亚造山带东段,其中前寒武的碎屑年龄在中国东北的多个陆块均有出现,可能源于早前存在的前寒武纪基底。本文测得侵入饶河杂岩的2个二长花岗岩形成年龄分别为126±1Ma和105±2Ma,表明饶河杂岩中的花岗岩脉主要形成于两个阶段,其中较老的花岗岩侵入体进一步限定了饶河杂岩的最终就位时代为133Ma至126Ma,表明古太平洋板块在中侏罗世至早白垩世存在西向俯冲-增生作用,为古太平洋板块的构造演化提供了重要的制约。  相似文献   

烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

An Automatic Method for Detecting Transients and Variable Sources in AST3 Survey Based on Image Subtraction and Random Forest     

《Chinese Astronomy and Astrophysics》2020,44(1):41-60

AST3-2 (the second Antarctic Survey Telescope) is located in Antarctic Dome A, the loftiest ice dome on the Antarctic Plateau. It produces a huge amount of observational data which require a more efficient data reduction program to be developed. Also the data transmission in Antarctica is much difficult, thus it is necessary to perform data reduction and detect variable and transient sources remotely and automatically in Antarctica, but this attempt is restricted by the unsatisfactory performance of the low power consumption computer in Antarctica. For realizing this purpose, to develop a new method based on the existing image subtraction method and random forest algorithm, taking the AST3-2 2016 dataset as the test sample, becomes an alternative choice. This method performs image subtraction on the dataset, then applies the principle component analysis to extract the features of residual images. Random forest is used as a machine learning classifier, and in the test a recall rate of 97% is resulted for the positive sample. Our work has verified the feasibility and accuracy of this method, and finally found out a batch of candidates for variable stars in the AST3-2 2016 dataset.  相似文献   

基于水资源约束的中国城镇化SD模型与模拟   总被引：1，自引：0，他引：1  

曹祺文  鲍超  顾朝林  管卫华 《地理研究》2019,38(1):167-180

中国城镇化正处于快速发展阶段,尽管经济和社会发展主控要素还在发挥重要作用,但水资源在生产、生活和生态方面发挥主控作用的局面愈益明显。在中国城镇化系统动力学（system dynamics,SD）模型基础上,从水资源供给、需求和水环境等层面将水资源作为主控要素嵌入原有模型中,拓展出基于水资源约束的中国城镇化SD模型,并对水资源利用进行了多情景模拟。结果表明：① 系统存流量和灵敏度检验证明模型模拟效果良好,具有可操作性。② 部门用水效率一定时,产业发展对水资源供需平衡的影响比人口增长更为明显。③ 在实行节水农业、节水工业、高生活需水、高生态环境需水和高再生水利用的综合协调方案中,2050年中国城镇化的发展约共需6789.70亿 m³水资源,基本实现水资源供需平衡。  相似文献   

京津冀夏季强降水下冰云宏微观特征          下载免费PDF全文

郑倩  郑有飞  王立稳  李特  林彤  杜傢义 《干旱区地理》2019,42(1):67-76

根据Aqua MODIS 2级云产品和Cloudsat的2级产品资料，结合降水数据和MODIS L1B级辐射率数据，对发生在京津冀地区夏季的三次强降水过程中冰云的宏微观物理量的特征进行分析，并探究这些物理量和降水强度的关系。结果表明：在水平分布中，强降水过程中降水强度高值区内云相为冰云，冰云云顶高度在8~17 km，冰云粒子有效半径、冰云光学厚度、冰水路径分别最高可达60 μm、 150、 5 000 g?m^-2；冰云光学厚度、冰水路径、冰云云顶高度随降水强度增大而增大。在垂直分布中，冰云主要分布在3.5 km以上，发生强降水站点的冰云为深对流云，冰云粒子有效半径、冰水含量、冰云粒子数浓度分别最高可达150 μm、 3 000 mg?m^-3 、 500 L^-1；冰云粒子有效半径高值区存在于云层中下部，且随高度上升而减小，冰云粒子数浓度高值区存在于云层中上部，且随高度上升而增加，冰水含量高值区则存在于云层中部；冰云粒子有效半径、冰水含量、冰云粒子数浓度在9 km以上随降水强度增大而增大。  相似文献   

韩国“新北方政策”对接“一带一路”倡议：机遇与挑战     

庞加欣  王灵桂 《热带地理》2019,39(6):911-918

韩国“新北方政策”与“一带一路”倡议的对接合作为中韩两国带来了重要发展机遇。文章主要探讨韩国“新北方政策”的内涵及其与“一带一路”倡议对接的进展、机遇与挑战,得出双方对接的合作机遇主要在政策沟通、设施联通、贸易投资和资金融通4个方面,同时也存在着制度性风险、地缘风险和投资合作风险的三大挑战。在具体对接过程中,产业、金融、物流3个领域可能成为突破口。  相似文献   

陆地可控源电磁法探测效果的频率响应          下载免费PDF全文

万伟  唐新功  黄清华 《地球物理学报》2019,62(12):4846-4859

陆地可控源电磁法的观测资料可依据频段范围近似地划分为近区场、中间区场及远区场,但采用测量相互正交电、磁分量,并计算视电阻率的资料处理方式只适用于远区场数据.为更有效地利用陆地可控源电磁法不同区间场的观测资料,本文结合三维数值模拟技术并采用电场分量直接进行反演的策略,对不同区间电场的响应特征与探测效果进行了分析.数值模拟结果表明:近区电场的异常响应最明显,异常响应不随频率发生显著变化,但纵向分辨能力差;远区电场异常响应随频率发生显著变化,其探测深度取决于频率的高低;中间区场较为复杂,地表电场异常响应的等值线中心并不是位于异常体中心正上方,而是在沿场传播方向上向异常体与围岩的分界面处偏移,并且发现中间区场资料的加入会影响反演结果的准确性.综合合成数据和野外实测资料的反演结果,发现结合近区场和远区场资料而舍弃中间区场资料的反演效果更佳,这为陆地可控源电磁法资料的反演解释提供了一种有效途径.  相似文献   

Temporal and Spatial Dynamics Analysis of Grassland Ecosystem Pressure in Kazakhstan     

WEN Xin  YAN Huimin  XIE Xiaoping  DU Wengpeng  LAI Chenxi  ZHEN Lin 《资源与生态学报(英文版)》2019,10(6):667-675

Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.  相似文献